{"id":4456,"date":"2025-06-02T05:17:53","date_gmt":"2025-06-02T05:17:53","guid":{"rendered":"https:\/\/diznr.com\/?p=4456"},"modified":"2025-06-02T05:17:53","modified_gmt":"2025-06-02T05:17:53","slug":"physical-chemistry-the-solid-state-type-of-crystalline-solid-ionic-covalent-metallic-part-3","status":"publish","type":"post","link":"https:\/\/www.reilsolar.com\/pdf\/physical-chemistry-the-solid-state-type-of-crystalline-solid-ionic-covalent-metallic-part-3\/","title":{"rendered":"Physical Chemistry &#8211; The Solid State-Type of Crystalline Solid- Ionic &#8211; Covalent &#8211; Metallic &#8211; part-3."},"content":{"rendered":"<p>Physical Chemistry &#8211; The Solid State-Type of Crystalline Solid- Ionic &#8211; Covalent &#8211; Metallic &#8211; part-3.<\/p>\n<p>[fvplayer id=&#8221;779&#8243;]<\/p>\n<h3 data-start=\"0\" data-end=\"49\"><strong data-start=\"4\" data-end=\"47\">\u00a0Physical Chemistry \u2013 The Solid State<\/strong><\/h3>\n<h3 data-start=\"50\" data-end=\"123\"><strong data-start=\"54\" data-end=\"121\">Types of Crystalline Solids: Ionic, Covalent, Metallic (Part-3)<\/strong><\/h3>\n<p data-start=\"125\" data-end=\"360\">Crystalline solids are <strong data-start=\"148\" data-end=\"166\">highly ordered<\/strong> structures where atoms, ions, or molecules are arranged in a <strong data-start=\"228\" data-end=\"258\">regular, repeating pattern<\/strong>. These solids can be classified into different types based on the <strong data-start=\"325\" data-end=\"357\">forces holding them together<\/strong>.<\/p>\n<h3 data-start=\"367\" data-end=\"414\"><strong data-start=\"370\" data-end=\"412\">\u00a01. Ionic Crystals (Ionic Solids) \ud83e\uddc2<\/strong><\/h3>\n<p data-start=\"415\" data-end=\"584\"><strong data-start=\"418\" data-end=\"444\">Constituent Particles:<\/strong> <strong data-start=\"445\" data-end=\"472\">Ions (Cations &amp; Anions)<\/strong><br data-start=\"472\" data-end=\"475\" \/><strong data-start=\"478\" data-end=\"496\">Bonding Force:<\/strong> <strong data-start=\"497\" data-end=\"535\">Electrostatic forces (Ionic bonds)<\/strong><br data-start=\"535\" data-end=\"538\" \/><strong data-start=\"541\" data-end=\"554\">Examples:<\/strong> NaCl (Salt), KCl, CaF\u2082, MgO<\/p>\n<h3 data-start=\"586\" data-end=\"625\"><strong data-start=\"590\" data-end=\"623\">\u00a0Properties of Ionic Solids<\/strong><\/h3>\n<p data-start=\"626\" data-end=\"898\"><strong data-start=\"628\" data-end=\"661\">High Melting &amp; Boiling Points<\/strong> (Strong electrostatic forces)<br data-start=\"691\" data-end=\"694\" \/><strong data-start=\"696\" data-end=\"714\">Hard &amp; Brittle<\/strong> (Ions are in fixed positions, break under stress)<br data-start=\"764\" data-end=\"767\" \/><strong data-start=\"769\" data-end=\"789\">Soluble in Water<\/strong> (Dissociates into ions)<br data-start=\"813\" data-end=\"816\" \/><strong data-start=\"818\" data-end=\"865\">Conducts Electricity in Molten\/Aqueous Form<\/strong> (Ions move freely in solution)<\/p>\n<p data-start=\"900\" data-end=\"1036\"><em data-start=\"903\" data-end=\"913\">Example:<\/em> <strong data-start=\"914\" data-end=\"940\">Sodium chloride (NaCl)<\/strong> forms a cubic lattice where <strong data-start=\"969\" data-end=\"984\">Na\u207a and Cl\u207b<\/strong> ions are held by strong <strong data-start=\"1009\" data-end=\"1033\">electrostatic forces<\/strong>.<\/p>\n<h3 data-start=\"1043\" data-end=\"1090\"><strong data-start=\"1046\" data-end=\"1088\">\u00a02. Covalent or Network Crystals\u00a0<\/strong><\/h3>\n<p data-start=\"1091\" data-end=\"1262\"><strong data-start=\"1094\" data-end=\"1120\">Constituent Particles:<\/strong> <strong data-start=\"1121\" data-end=\"1130\">Atoms<\/strong><br data-start=\"1130\" data-end=\"1133\" \/><strong data-start=\"1136\" data-end=\"1154\">Bonding Force:<\/strong> <strong data-start=\"1155\" data-end=\"1195\">Covalent Bonds (Strongest bond type)<\/strong><br data-start=\"1195\" data-end=\"1198\" \/><strong data-start=\"1201\" data-end=\"1214\">Examples:<\/strong> Diamond (C), Graphite (C), SiO\u2082 (Quartz), SiC<\/p>\n<h3 data-start=\"1264\" data-end=\"1306\"><strong data-start=\"1268\" data-end=\"1304\">\u00a0Properties of Covalent Solids<\/strong><\/h3>\n<p data-start=\"1307\" data-end=\"1558\"><strong data-start=\"1309\" data-end=\"1337\">Extremely Hard &amp; Brittle<\/strong> (Due to strong covalent bonding)<br data-start=\"1370\" data-end=\"1373\" \/><strong data-start=\"1375\" data-end=\"1403\">Very High Melting Points<\/strong> (Breaking covalent bonds requires a lot of energy)<br data-start=\"1454\" data-end=\"1457\" \/><strong data-start=\"1459\" data-end=\"1492\">Non-Conductors of Electricity<\/strong> (No free electrons, except graphite)<br data-start=\"1529\" data-end=\"1532\" \/><strong data-start=\"1534\" data-end=\"1556\">Insoluble in Water<\/strong><\/p>\n<p data-start=\"1560\" data-end=\"1813\"><em data-start=\"1563\" data-end=\"1573\">Example:<\/em> <strong data-start=\"1574\" data-end=\"1585\">Diamond<\/strong> has a <strong data-start=\"1592\" data-end=\"1618\">3D tetrahedral network<\/strong> of carbon atoms, making it <strong data-start=\"1646\" data-end=\"1679\">the hardest natural substance<\/strong>. In contrast, <strong data-start=\"1694\" data-end=\"1706\">graphite<\/strong> has <strong data-start=\"1711\" data-end=\"1739\">layered hexagonal sheets<\/strong> that slide over each other, making it a <strong data-start=\"1780\" data-end=\"1810\">good lubricant &amp; conductor<\/strong>.<\/p>\n<h3 data-start=\"1820\" data-end=\"1873\"><strong data-start=\"1823\" data-end=\"1871\">\u00a03. Metallic Crystals (Metallic Solids)\u00a0<\/strong><\/h3>\n<p data-start=\"1874\" data-end=\"2055\"><strong data-start=\"1877\" data-end=\"1903\">Constituent Particles:<\/strong> <strong data-start=\"1904\" data-end=\"1919\">Metal Atoms<\/strong><br data-start=\"1919\" data-end=\"1922\" \/><strong data-start=\"1925\" data-end=\"1943\">Bonding Force:<\/strong> <strong data-start=\"1944\" data-end=\"1983\">Metallic Bonds (Electron Sea Model)<\/strong><br data-start=\"1983\" data-end=\"1986\" \/><strong data-start=\"1989\" data-end=\"2002\">Examples:<\/strong> Fe (Iron), Cu (Copper), Al (Aluminum), Ag (Silver)<\/p>\n<h3 data-start=\"2057\" data-end=\"2099\"><strong data-start=\"2061\" data-end=\"2097\">\u00a0Properties of Metallic Solids<\/strong><\/h3>\n<p data-start=\"2100\" data-end=\"2367\"><strong data-start=\"2102\" data-end=\"2143\">Good Conductors of Electricity &amp; Heat<\/strong> (Free-moving electrons)<br data-start=\"2167\" data-end=\"2170\" \/><strong data-start=\"2172\" data-end=\"2195\">Malleable &amp; Ductile<\/strong> (Layers of atoms slide over each other)<br data-start=\"2235\" data-end=\"2238\" \/><strong data-start=\"2240\" data-end=\"2260\">Lustrous (Shiny)<\/strong> (Light reflection from free electrons)<br data-start=\"2299\" data-end=\"2302\" \/><strong data-start=\"2304\" data-end=\"2341\">Variable Melting &amp; Boiling Points<\/strong> (Depends on metal type)<\/p>\n<p data-start=\"2369\" data-end=\"2476\"><em data-start=\"2372\" data-end=\"2382\">Example:<\/em> <strong data-start=\"2383\" data-end=\"2398\">Copper (Cu)<\/strong> is used in <strong data-start=\"2410\" data-end=\"2419\">wires<\/strong> due to its <strong data-start=\"2431\" data-end=\"2452\">high conductivity<\/strong> and <strong data-start=\"2457\" data-end=\"2473\">malleability<\/strong>.<\/p>\n<h3 data-start=\"2483\" data-end=\"2530\"><strong data-start=\"2486\" data-end=\"2528\">\u00a0Summary Table of Crystalline Solids<\/strong><\/h3>\n<table style=\"width: 94.6791%\" data-start=\"2532\" data-end=\"3021\">\n<thead data-start=\"2532\" data-end=\"2612\">\n<tr data-start=\"2532\" data-end=\"2612\">\n<th style=\"width: 14.5072%\" data-start=\"2532\" data-end=\"2552\"><strong data-start=\"2534\" data-end=\"2551\">Type of Solid<\/strong><\/th>\n<th style=\"width: 18.6047%\" data-start=\"2552\" data-end=\"2579\"><strong data-start=\"2554\" data-end=\"2578\">Forces of Attraction<\/strong><\/th>\n<th style=\"width: 43.8538%\" data-start=\"2579\" data-end=\"2596\"><strong data-start=\"2581\" data-end=\"2595\">Properties<\/strong><\/th>\n<th style=\"width: 21.8162%\" data-start=\"2596\" data-end=\"2612\"><strong data-start=\"2598\" data-end=\"2610\">Examples<\/strong><\/th>\n<\/tr>\n<\/thead>\n<tbody data-start=\"2687\" data-end=\"3021\">\n<tr data-start=\"2687\" data-end=\"2800\">\n<td style=\"width: 14.5072%\"><strong data-start=\"2689\" data-end=\"2705\">Ionic Solids<\/strong><\/td>\n<td style=\"width: 18.6047%\">Electrostatic Forces<\/td>\n<td style=\"width: 43.8538%\">Hard, Brittle, High MP, Conductive in liquid state<\/td>\n<td style=\"width: 21.8162%\">NaCl, KCl, MgO<\/td>\n<\/tr>\n<tr data-start=\"2801\" data-end=\"2924\">\n<td style=\"width: 14.5072%\"><strong data-start=\"2803\" data-end=\"2822\">Covalent Solids<\/strong><\/td>\n<td style=\"width: 18.6047%\">Covalent Bonds<\/td>\n<td style=\"width: 43.8538%\">Very Hard, High MP, Non-Conductive (except graphite)<\/td>\n<td style=\"width: 21.8162%\">Diamond, Quartz, Graphite<\/td>\n<\/tr>\n<tr data-start=\"2925\" data-end=\"3021\">\n<td style=\"width: 14.5072%\"><strong data-start=\"2927\" data-end=\"2946\">Metallic Solids<\/strong><\/td>\n<td style=\"width: 18.6047%\">Metallic Bonds<\/td>\n<td style=\"width: 43.8538%\">Conductive, Malleable, Ductile, Lustrous<\/td>\n<td style=\"width: 21.8162%\">Fe, Cu, Ag<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h3 data-start=\"3028\" data-end=\"3050\"><strong data-start=\"3031\" data-end=\"3048\">\u00a0Conclusion<\/strong><\/h3>\n<p data-start=\"3051\" data-end=\"3271\">Understanding <strong data-start=\"3065\" data-end=\"3105\">ionic, covalent, and metallic solids<\/strong> helps in <strong data-start=\"3115\" data-end=\"3140\">predicting properties<\/strong> like hardness, conductivity, and solubility. These concepts are <strong data-start=\"3205\" data-end=\"3268\">fundamental in chemistry, material science, and engineering<\/strong>.<\/p>\n<p data-start=\"3273\" data-end=\"3339\" data-is-last-node=\"\" data-is-only-node=\"\">\u00a0<strong data-start=\"3276\" data-end=\"3336\">Got any questions about crystalline solids? Let me know!<\/strong><\/p>\n<h3 data-start=\"3273\" data-end=\"3339\"><a href=\"https:\/\/www.nios.ac.in\/media\/documents\/SrSec313NEW\/313_Chemistry_Eng\/313_Chemistry_Eng_Lesson6.pdf\" target=\"_blank\" rel=\"noopener\">Physical Chemistry &#8211; The Solid State-Type of Crystalline Solid- Ionic &#8211; Covalent &#8211; Metallic &#8211; part-3.<\/a><\/h3>\n<h3 class=\"LC20lb MBeuO DKV0Md\"><a href=\"https:\/\/www.hrmrajgurunagar.ac.in\/uploads\/student_corner\/3__Ionic_Solids_.pdf\" target=\"_blank\" rel=\"noopener\">II Inorganic Chemistry Sem- IV Chapter -3. Ionic Solids<\/a><\/h3>\n<h3 class=\"LC20lb MBeuO DKV0Md\"><a href=\"https:\/\/gjcollegebihta.ac.in\/assets\/econtent\/chemistry\/THE%20SOLID%20STATE%20PHYSICAL%20CHEMISTRY%20B.Sc%20ll%20(H).pdf\" target=\"_blank\" rel=\"noopener\">PHYSICAL CHEMISTRY &#8211; [THE SOLID STATE &#8211; B.Sc<\/a><\/h3>\n<h3 class=\"LC20lb MBeuO DKV0Md\"><a href=\"https:\/\/www.chem.uci.edu\/~lawm\/10-19.pdf\" target=\"_blank\" rel=\"noopener\">The Crystalline Solid State<\/a><\/h3>\n<h3 class=\"LC20lb MBeuO DKV0Md\"><a href=\"https:\/\/faculty.ksu.edu.sa\/sites\/default\/files\/the_solid_state.pdf\" target=\"_blank\" rel=\"noopener\">The Solid Stat The Solid State<\/a><\/h3>\n<p>Here&#8217;s a concise and student-friendly explanation of <strong>Physical Chemistry \u2013 The Solid State (Part-3): Types of Crystalline Solids<\/strong>, covering <strong>Ionic, Covalent, and Metallic Solids<\/strong>, useful for CBSE, NEET, JEE, or general Chemistry learning.<\/p>\n<hr \/>\n<h2>\ud83d\udcd8 <strong>The Solid State \u2013 Types of Crystalline Solids (Part-3)<\/strong><\/h2>\n<p>Crystalline solids have <strong>definite shapes and patterns<\/strong> because their particles are arranged in <strong>an orderly three-dimensional pattern<\/strong>.<\/p>\n<hr \/>\n<h3>\ud83d\udd39 <strong>1. Ionic Solids<\/strong><\/h3>\n<p><strong>\ud83d\udd38Definition:<\/strong><br \/>\nMade of <strong>positive and negative ions<\/strong> held together by <strong>strong electrostatic forces of attraction<\/strong>.<\/p>\n<p><strong>\ud83d\udd2c Examples:<\/strong> NaCl (Sodium chloride), KBr, MgO<\/p>\n<p><strong>\ud83e\uddea Properties:<\/strong><\/p>\n<ul>\n<li><strong>High melting and boiling points<\/strong><\/li>\n<li><strong>Hard and brittle<\/strong><\/li>\n<li><strong>Conduct electricity in molten or aqueous state<\/strong> (not in solid state)<\/li>\n<li><strong>Soluble in water,<\/strong> not in organic solvents<\/li>\n<\/ul>\n<p><strong>\ud83c\udf93 Application Tip:<\/strong> Most <strong>salts<\/strong> are ionic solids.<\/p>\n<hr \/>\n<h3>\ud83d\udd39 <strong>2. Covalent (or Network) Solids<\/strong><\/h3>\n<p><strong>\ud83d\udd38Definition:<\/strong><br \/>\nAtoms are bonded by <strong>strong covalent bonds<\/strong> throughout the crystal in a network.<\/p>\n<p><strong>\ud83d\udd2c Examples:<\/strong> Diamond (C), Silicon carbide (SiC), Quartz (SiO\u2082)<\/p>\n<p><strong>\ud83e\uddea Properties:<\/strong><\/p>\n<ul>\n<li><strong>Very hard and brittle<\/strong> (e.g., diamond is the hardest known substance)<\/li>\n<li><strong>Extremely high melting points<\/strong><\/li>\n<li><strong>Do not conduct electricity<\/strong> (except graphite)<\/li>\n<li><strong>Insoluble in all solvents<\/strong><\/li>\n<\/ul>\n<p><strong>\ud83d\udca1 Special Case \u2013 Graphite:<\/strong><\/p>\n<ul>\n<li>Though covalent, graphite conducts electricity due to <strong>free electrons (delocalized \u03c0-electrons)<\/strong> between layers.<\/li>\n<\/ul>\n<hr \/>\n<h3>\ud83d\udd39 <strong>3. Metallic Solids<\/strong><\/h3>\n<p><strong>\ud83d\udd38Definition:<\/strong><br \/>\nMade up of <strong>positive metal ions in a &#8216;sea&#8217; of mobile electrons<\/strong>.<\/p>\n<p><strong>\ud83d\udd2c Examples:<\/strong> Fe, Cu, Ag, Al, Zn<\/p>\n<p><strong>\ud83e\uddea Properties:<\/strong><\/p>\n<ul>\n<li><strong>Good conductors of heat and electricity<\/strong><\/li>\n<li><strong>Malleable and ductile<\/strong><\/li>\n<li><strong>Lustrous (shiny)<\/strong><\/li>\n<li><strong>Range of melting points<\/strong><\/li>\n<\/ul>\n<p><strong>\ud83c\udf93 Application Tip:<\/strong> Most metals used in industry and electrical applications fall in this category.<\/p>\n<hr \/>\n<h3>\ud83d\udcca <strong>Quick Comparison Table<\/strong><\/h3>\n<table>\n<thead>\n<tr>\n<th>Property<\/th>\n<th>Ionic Solid<\/th>\n<th>Covalent Solid<\/th>\n<th>Metallic Solid<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>Bond Type<\/td>\n<td>Ionic<\/td>\n<td>Covalent<\/td>\n<td>Metallic<\/td>\n<\/tr>\n<tr>\n<td>Melting Point<\/td>\n<td>High<\/td>\n<td>Very High<\/td>\n<td>Variable<\/td>\n<\/tr>\n<tr>\n<td>Electrical Conduct.<\/td>\n<td>In molten\/solution<\/td>\n<td>No (Graphite: Yes)<\/td>\n<td>Yes (in solid state)<\/td>\n<\/tr>\n<tr>\n<td>Hardness<\/td>\n<td>Hard, brittle<\/td>\n<td>Very hard (except graphite)<\/td>\n<td>Malleable &amp; ductile<\/td>\n<\/tr>\n<tr>\n<td>Solubility<\/td>\n<td>Water-soluble<\/td>\n<td>Insoluble<\/td>\n<td>Insoluble (generally)<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<hr \/>\n<h3>\ud83e\udde0 <strong>Mnemonic to Remember<\/strong> \u2013 <strong>\u201cI Can Make\u201d<\/strong><\/h3>\n<ul>\n<li><strong>I<\/strong> = Ionic<\/li>\n<li><strong>C<\/strong> = Covalent<\/li>\n<li><strong>M<\/strong> = Metallic<\/li>\n<\/ul>\n<hr \/>\n<h3>\u2705 <strong>Would you like a PDF with diagrams, MCQs, and concept maps for this topic?<\/strong><\/h3>\n<p>Let me know your class\/board (CBSE, ICSE, State Board), and I\u2019ll prepare a custom study sheet for you!<\/p>\n<h3><a href=\"https:\/\/www.sjctni.edu\/Department\/ch\/eLecture\/Solid%20State.pdf\" target=\"_blank\" rel=\"noopener\">Physical Chemistry &#8211; The Solid State-Type of Crystalline Solid- Ionic &#8211; Covalent &#8211; Metallic &#8211; part-3.<\/a><\/h3>\n<h3 class=\"LC20lb MBeuO DKV0Md\"><a href=\"https:\/\/eguru.rrbdavc.org\/module\/data\/233-Types%20of%20Solids.pdf\" target=\"_blank\" rel=\"noopener\">TYPES OF SOLIDS<\/a><\/h3>\n","protected":false},"excerpt":{"rendered":"<p>Physical Chemistry &#8211; The Solid State-Type of Crystalline Solid- Ionic &#8211; Covalent &#8211; Metallic &#8211; part-3. [fvplayer id=&#8221;779&#8243;] \u00a0Physical Chemistry \u2013 The Solid State Types of Crystalline Solids: Ionic, Covalent, Metallic (Part-3) Crystalline solids are highly ordered structures where atoms, ions, or molecules are arranged in a regular, repeating pattern. These solids can be classified [&hellip;]<\/p>\n","protected":false},"author":64,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[17,18,105],"tags":[],"class_list":["post-4456","post","type-post","status-publish","format-standard","hentry","category-class-11-and-12-physical-chemistry","category-iit-neet-chemistry","category-physical-chemistry"],"_links":{"self":[{"href":"https:\/\/www.reilsolar.com\/pdf\/wp-json\/wp\/v2\/posts\/4456","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.reilsolar.com\/pdf\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.reilsolar.com\/pdf\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.reilsolar.com\/pdf\/wp-json\/wp\/v2\/users\/64"}],"replies":[{"embeddable":true,"href":"https:\/\/www.reilsolar.com\/pdf\/wp-json\/wp\/v2\/comments?post=4456"}],"version-history":[{"count":0,"href":"https:\/\/www.reilsolar.com\/pdf\/wp-json\/wp\/v2\/posts\/4456\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.reilsolar.com\/pdf\/wp-json\/wp\/v2\/media?parent=4456"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.reilsolar.com\/pdf\/wp-json\/wp\/v2\/categories?post=4456"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.reilsolar.com\/pdf\/wp-json\/wp\/v2\/tags?post=4456"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}